[guided]The only point that needs checking is that the formula respects the algebra structure of the unitization. Let $(a,\lambda),(b,\mu)\in A^+$ and let $\alpha,\beta\in\mathbb C$. The [vector space](/page/Vector%20Space) structure on $A^+=A\oplus\mathbb C$ is componentwise, so
\begin{align*}
\alpha(a,\lambda)+\beta(b,\mu)=(\alpha a+\beta b,\alpha\lambda+\beta\mu).
\end{align*}
Using linearity of $\pi:A\to B$, we obtain
\begin{align*}
\pi^+(\alpha(a,\lambda)+\beta(b,\mu))=\pi(\alpha a+\beta b)+(\alpha\lambda+\beta\mu)1_B.
\end{align*}
This equals
\begin{align*}
\alpha(\pi(a)+\lambda1_B)+\beta(\pi(b)+\mu1_B)=\alpha\pi^+(a,\lambda)+\beta\pi^+(b,\mu).
\end{align*}
Thus $\pi^+$ is linear.
Now we check multiplication. The product in the standard unitization is
\begin{align*}
(a,\lambda)(b,\mu)=(ab+\lambda b+\mu a,\lambda\mu).
\end{align*}
Applying $\pi^+$ gives
\begin{align*}
\pi^+((a,\lambda)(b,\mu))=\pi(ab+\lambda b+\mu a)+\lambda\mu1_B.
\end{align*}
Because $\pi$ is a $*$-homomorphism, it is linear and multiplicative. Therefore this becomes
\begin{align*}
\pi(a)\pi(b)+\lambda\pi(b)+\mu\pi(a)+\lambda\mu1_B.
\end{align*}
On the other hand, multiplying the two proposed images in the unital algebra $B$ gives
\begin{align*}
\pi^+(a,\lambda)\pi^+(b,\mu)=(\pi(a)+\lambda1_B)(\pi(b)+\mu1_B).
\end{align*}
Expanding in $B$ and using that $1_B$ is the identity gives the same expression:
\begin{align*}
\pi^+(a,\lambda)\pi^+(b,\mu)=\pi(a)\pi(b)+\lambda\pi(b)+\mu\pi(a)+\lambda\mu1_B.
\end{align*}
Hence $\pi^+$ preserves multiplication.
Finally, the involution in $A^+$ is
\begin{align*}
(a,\lambda)^*=(a^*,\overline{\lambda}).
\end{align*}
Since $\pi$ preserves adjoints,
\begin{align*}
\pi^+((a,\lambda)^*)=\pi(a^*)+\overline{\lambda}1_B=\pi(a)^*+\overline{\lambda}1_B.
\end{align*}
Because $1_B^*=1_B$, this equals
\begin{align*}
(\pi(a)+\lambda1_B)^*=\pi^+(a,\lambda)^*.
\end{align*}
Together with $\pi^+(0,1)=1_B$, this proves that $\pi^+$ is a unital $*$-homomorphism.[/guided]