[guided]The point of this step is to make the compatibility with direct sums completely explicit, because this compatibility is what later makes localization descend to $K_0$. Let $M$ and $N$ be $R$-modules. We define
\begin{align*}
\Theta_{M,N}:S^{-1}(M\oplus N)\to S^{-1}M\oplus S^{-1}N
\end{align*}
by
\begin{align*}
\Theta_{M,N}\left(\frac{(m,n)}{s}\right)=\left(\frac{m}{s},\frac{n}{s}\right).
\end{align*}
This map separates the two components after localization.
Conversely, if two localized elements have different denominators, we combine them by passing to a common denominator. Define
\begin{align*}
\Psi_{M,N}:S^{-1}M\oplus S^{-1}N\to S^{-1}(M\oplus N)
\end{align*}
by
\begin{align*}
\Psi_{M,N}\left(\frac{m}{s},\frac{n}{t}\right)=\frac{(tm,sn)}{st}.
\end{align*}
The denominator $st$ lies in $S$ because $S$ is multiplicative. The numerator $(tm,sn)$ lies in $M\oplus N$ because $M$ and $N$ are $R$-modules.
We now verify that these two maps are inverse. Starting from $\left(\frac{m}{s},\frac{n}{t}\right)$, we compute
\begin{align*}
\Theta_{M,N}\left(\Psi_{M,N}\left(\frac{m}{s},\frac{n}{t}\right)\right)=\Theta_{M,N}\left(\frac{(tm,sn)}{st}\right).
\end{align*}
Hence
\begin{align*}
\Theta_{M,N}\left(\Psi_{M,N}\left(\frac{m}{s},\frac{n}{t}\right)\right)=\left(\frac{tm}{st},\frac{sn}{st}\right)=\left(\frac{m}{s},\frac{n}{t}\right).
\end{align*}
Starting from $\frac{(m,n)}{s}$, we compute
\begin{align*}
\Psi_{M,N}\left(\Theta_{M,N}\left(\frac{(m,n)}{s}\right)\right)=\Psi_{M,N}\left(\frac{m}{s},\frac{n}{s}\right).
\end{align*}
Therefore
\begin{align*}
\Psi_{M,N}\left(\Theta_{M,N}\left(\frac{(m,n)}{s}\right)\right)=\frac{(sm,sn)}{s^2}=\frac{(m,n)}{s}.
\end{align*}
Thus $S^{-1}(M\oplus N)\cong S^{-1}M\oplus S^{-1}N$ as $A$-modules.[/guided]