[guided]We begin with a tangent vector $X\in\mathfrak g=T_eG$. The only natural way to create a vector at an arbitrary point $g\in G$ from $X$ is to use left translation. For each $g\in G$, left translation is the smooth map $L_g:G\to G$, $h\mapsto gh$. Its differential at the identity is a [linear map](/page/Linear%20Map) $(dL_g)_e:T_eG\to T_gG$. Thus the formula $\widetilde X_g=(dL_g)_e(X)$ really does define an element of the correct tangent space $T_gG$ for every $g\in G$.
The main point is smoothness in the variable $g$. By the curve characterization of tangent vectors on a smooth manifold, choose a smooth curve $c:(-\varepsilon,\varepsilon)\to G$ with $c(0)=e$ and $c'(0)=X$. Such a curve represents the tangent vector $X$ at $e$. Now define $F:G\times(-\varepsilon,\varepsilon)\to G$ by $F(g,t)=gc(t)$. This map is smooth because $G$ is a Lie group: multiplication $G\times G\to G$ is smooth, and $(g,t)\mapsto (g,c(t))$ is smooth.
For fixed $g\in G$, the curve $t\mapsto F(g,t)=gc(t)$ is exactly $L_g\circ c$. Therefore its velocity at $t=0$ is
\begin{align*}
\frac{d}{dt}\Big|_{t=0}F(g,t)=\frac{d}{dt}\Big|_{t=0}(L_g\circ c)(t)=(dL_g)_e(c'(0))=(dL_g)_e(X)=\widetilde X_g.
\end{align*}
So $\widetilde X_g$ is obtained by differentiating a smooth family of curves with respect to the parameter $t$ at $t=0$.
To see that this produces a smooth vector field, fix a point $g_0\in G$ and choose a smooth coordinate chart $(U,\varphi)$ with $g_0\in U$. We need the family $F(g,t)$ to remain inside this chart before we write coordinate functions. Since $F(g_0,0)=g_0$ and $F$ is continuous, there are an open neighbourhood $V\subset G$ of $g_0$ and a number $\delta\in(0,\varepsilon)$ such that $F(V\times(-\delta,\delta))\subset U$.
Now the coordinate expression $\varphi\circ F:V\times(-\delta,\delta)\to\mathbb R^n$ is smooth. Its [partial derivative](/page/Partial%20Derivative) with respect to $t$ at $t=0$ exists and depends smoothly on $g\in V$. These partial derivatives are exactly the coordinate components of the tangent vector $\widetilde X_g$, because $\widetilde X_g$ is the velocity at $t=0$ of the curve $t\mapsto F(g,t)$. Hence the coordinate components of $\widetilde X$ are smooth on $V$. Since $g_0$ was arbitrary, $\widetilde X$ is smooth on all of $G$.[/guided]