On $\partial B(x,\varepsilon)$ (with $\nu$ pointing into $B(x,\varepsilon)$): $u(y) = G(x,y) = \Phi(y-x) - \phi^x(y)$ has a singularity like $\Phi$ as $y \to x$, while $v(y) = G(z,y)$ is smooth near $x$. The same computation as in the proof of the [Green's Representation Formula](/theorems/567) gives, as $\varepsilon \to 0$:
\begin{align*}
\int_{\partial B(x,\varepsilon)} \Bigl(u\,\frac{\partial v}{\partial\nu} - v\,\frac{\partial u}{\partial\nu}\Bigr)\,d\mathcal{H}^{n-1} &\to -v(x) = -G(z,x).
\end{align*}
By the identical argument on $\partial B(z,\varepsilon)$ with the roles of $u$ and $v$ exchanged:
\begin{align*}
\int_{\partial B(z,\varepsilon)} \Bigl(u\,\frac{\partial v}{\partial\nu} - v\,\frac{\partial u}{\partial\nu}\Bigr)\,d\mathcal{H}^{n-1} &\to u(z) = G(x,z).
\end{align*}
Hence $0 = -G(z,x) + G(x,z)$, giving $G(x,z) = G(z,x)$.
[/proof]