[guided]We first need to prove that the formulas in the statement actually define operations on $\operatorname{End}_F(V)$, not merely on all functions $V \to V$. This means that whenever $S$ and $T$ are $F$-linear maps from $V$ to $V$, their pointwise sum must again be an $F$-[linear map](/page/Linear%20Map) from $V$ to $V$.
Let $S,T \in \operatorname{End}_F(V)$ and define
\begin{align*}
A: V \to V,\quad v \mapsto S(v)+T(v).
\end{align*}
The codomain is $V$ because $S(v),T(v) \in V$ and $V$ is closed under vector addition. To check $F$-linearity, let $\lambda \in F$ and $v,w \in V$. Since $S$ and $T$ are $F$-linear,
\begin{align*}
S(\lambda v+w)=\lambda S(v)+S(w).
\end{align*}
\begin{align*}
T(\lambda v+w)=\lambda T(v)+T(w).
\end{align*}
Substituting these two identities into the definition of $A$ gives
\begin{align*}
A(\lambda v+w)=S(\lambda v+w)+T(\lambda v+w)=\lambda S(v)+S(w)+\lambda T(v)+T(w).
\end{align*}
Using associativity and commutativity of addition in the vector space $V$, we regroup the right-hand side as
\begin{align*}
\lambda S(v)+S(w)+\lambda T(v)+T(w)=\lambda(S(v)+T(v))+(S(w)+T(w))=\lambda A(v)+A(w).
\end{align*}
Hence $A$ is $F$-linear, so $S+T=A$ lies in $\operatorname{End}_F(V)$.
Now let $a \in F$ and define
\begin{align*}
B: V \to V,\quad v \mapsto aT(v).
\end{align*}
Again the codomain is $V$ because scalar multiplication by $a$ sends vectors of $V$ to vectors of $V$. For $\lambda \in F$ and $v,w \in V$, the linearity of $T$ gives
\begin{align*}
B(\lambda v+w)=aT(\lambda v+w)=a(\lambda T(v)+T(w)).
\end{align*}
Distributing scalar multiplication over vector addition in $V$ gives
\begin{align*}
a(\lambda T(v)+T(w))=a\lambda T(v)+aT(w).
\end{align*}
Since $F$ is a field, its multiplication is commutative, so $a\lambda=\lambda a$. Therefore
\begin{align*}
a\lambda T(v)+aT(w)=\lambda aT(v)+aT(w)=\lambda B(v)+B(w).
\end{align*}
Thus $B$ is $F$-linear, so $aT=B$ lies in $\operatorname{End}_F(V)$.
It remains in this step to justify the vector space axioms. The zero vector in $\operatorname{End}_F(V)$ is the zero map
\begin{align*}
0_{\operatorname{End}}: V \to V,\quad v \mapsto 0_V.
\end{align*}
This map is $F$-linear because $0_{\operatorname{End}}(\lambda v+w)=0_V=\lambda 0_V+0_V$. The additive inverse of $T$ is the map
\begin{align*}
-T: V \to V,\quad v \mapsto -T(v),
\end{align*}
which is $F$-linear by the scalar-multiple argument with scalar $-1_F$.
For the remaining axioms, such as associativity and commutativity of addition, distributivity of scalar multiplication over addition, and the scalar identity law, equality of maps reduces the verification to pointwise equality. For example, for $R,S,T \in \operatorname{End}_F(V)$ and $v \in V$,
\begin{align*}
((R+S)+T)(v)=(R(v)+S(v))+T(v)=R(v)+(S(v)+T(v))=(R+(S+T))(v).
\end{align*}
The middle equality is associativity of addition in $V$. The other vector space axioms are verified in the same pointwise way from the corresponding axioms in $V$. Therefore $\operatorname{End}_F(V)$ is an $F$-vector space.[/guided]