[step:Identify the density and verify the heat equation]
For $t>0$, define the map $\rho:(0,\infty)\times\mathbb R^n\to[0,\infty)$ by
\begin{align*}
\rho(t,x)=\int_{\mathbb R^n}G_t(x-y)\,d\mu_0(y).
\end{align*}
For each fixed $t>0$, Tonelli's theorem gives
\begin{align*}
\int_{\mathbb R^n}\rho(t,x)\,d\mathcal L^n(x)=\int_{\mathbb R^n}\int_{\mathbb R^n}G_t(x-y)\,d\mathcal L^n(x)\,d\mu_0(y)=1,
\end{align*}
because $G_t$ integrates to $1$ with respect to $\mathcal L^n$. Hence $\rho_t:=\rho(t,\cdot)$ is a probability density and $\mu_t=\rho_t\,\mathcal L^n$.
We next verify smoothness and the heat equation. Fix $0<a<b<\infty$ and a compact set $K\subset\mathbb R^n$. For every multi-index $\alpha\in\mathbb N_0^n$ and every integer $m\ge0$, the function
\begin{align*}
(t,x,y)\mapsto \partial_t^m D_x^\alpha G_t(x-y)
\end{align*}
is continuous on $[a,b]\times K\times\mathbb R^n$ and is bounded there by a finite constant depending on $a$, $b$, $K$, $m$, and $\alpha$. Differentiation under the integral sign with respect to the finite measure $\mu_0$ therefore gives $\rho\in C^\infty((0,\infty)\times\mathbb R^n)$ and
\begin{align*}
\partial_t\rho(t,x)=\int_{\mathbb R^n}\partial_tG_t(x-y)\,d\mu_0(y),
\end{align*}
while
\begin{align*}
\Delta\rho(t,x)=\int_{\mathbb R^n}\Delta_xG_t(x-y)\,d\mu_0(y).
\end{align*}
A direct differentiation of the Gaussian kernel gives
\begin{align*}
\partial_tG_t(\xi)=\Delta_\xi G_t(\xi)
\end{align*}
for every $t>0$ and every $\xi\in\mathbb R^n$. Since $\Delta_xG_t(x-y)=\Delta_\xi G_t(\xi)$ at $\xi=x-y$, it follows that
\begin{align*}
\partial_t\rho(t,x)=\Delta\rho(t,x)
\end{align*}
for every $(t,x)\in(0,\infty)\times\mathbb R^n$.
[/step]