[guided]The point of this step is to justify carefully why the graphical conditional independence, which is stated with $X$ in the conditioning set, implies the theorem's displayed equality without $X$ in the conditioning set. Under the intervention $do(X=x)$, the interventional law $P_x$ is concentrated on the event $\{X=x\}$:
\begin{align*}
P_x(X=x)=1.
\end{align*}
Consequently, for any event $E$ determined by the remaining variables, intersecting with $\{X=x\}$ does not change its probability:
\begin{align*}
P_x(E \cap \{X=x\})=P_x(E).
\end{align*}
Indeed, the difference between $E$ and $E \cap \{X=x\}$ is contained in $\{X\ne x\}$, which has $P_x$-probability zero.
Apply this observation first to $E=\{Z=z,W=w\}$. The positivity hypothesis gives
\begin{align*}
P_x(Z=z,W=w)>0,
\end{align*}
and therefore
\begin{align*}
P_x(X=x,Z=z,W=w)=P_x(Z=z,W=w)>0.
\end{align*}
Thus $P_x(Y=y \mid X=x,Z=z,W=w)$ is defined. Its definition is
\begin{align*}
P_x(Y=y \mid X=x,Z=z,W=w)=\frac{P_x(Y=y,X=x,Z=z,W=w)}{P_x(X=x,Z=z,W=w)}.
\end{align*}
Using again that $P_x(X=x)=1$, the numerator and denominator reduce to
\begin{align*}
P_x(Y=y,X=x,Z=z,W=w)=P_x(Y=y,Z=z,W=w)
\end{align*}
and
\begin{align*}
P_x(X=x,Z=z,W=w)=P_x(Z=z,W=w).
\end{align*}
Therefore
\begin{align*}
P_x(Y=y \mid X=x,Z=z,W=w)=P_x(Y=y \mid Z=z,W=w).
\end{align*}
Now apply the same null-complement observation to the event $\{W=w\}$. Since
\begin{align*}
P_x(W=w)>0,
\end{align*}
we also have
\begin{align*}
P_x(X=x,W=w)=P_x(W=w)>0.
\end{align*}
Hence
\begin{align*}
P_x(Y=y \mid X=x,W=w)=\frac{P_x(Y=y,X=x,W=w)}{P_x(X=x,W=w)}.
\end{align*}
The intervention degeneracy gives
\begin{align*}
P_x(Y=y,X=x,W=w)=P_x(Y=y,W=w)
\end{align*}
and
\begin{align*}
P_x(X=x,W=w)=P_x(W=w),
\end{align*}
so
\begin{align*}
P_x(Y=y \mid X=x,W=w)=P_x(Y=y \mid W=w).
\end{align*}
This is the precise algebraic reason that conditioning on the intervened value $X=x$ can be removed under the law $P_x$.[/guided]