[step:Extract the matrix coefficient integral from a rank-one map]
Fix indices $1\leq j\leq m$ and $1\leq b\leq n$. Define the rank-one linear map
\begin{align*}
A_{jb}:W\to V
\end{align*}
by
\begin{align*}
A_{jb}x=(x,w_b)_Wv_j.
\end{align*}
Equivalently, $A_{jb}w_b=v_j$ and $A_{jb}w_c=0$ for $c\neq b$.
For $1\leq a\leq n$ and $1\leq i\leq m$, compute the $(i,a)$ matrix coefficient of $T_{A_{jb}}$:
\begin{align*}
(T_{A_{jb}}w_a,v_i)_V=\int_G (\rho(g)A_{jb}\sigma(g)^{-1}w_a,v_i)_V\,d\mu(g).
\end{align*}
For a linear map $B:W\to W$, write $B^*:W\to W$ for the adjoint with respect to $(\cdot,\cdot)_W$. Since $\sigma$ is unitary, $\sigma(g)^{-1}=\sigma(g)^*$. With the convention that the [inner product](/page/Inner%20Product) is linear in the first argument,
\begin{align*}
(\sigma(g)^{-1}w_a,w_b)_W=(w_a,\sigma(g)w_b)_W=\overline{(\sigma(g)w_b,w_a)_W}=\overline{\sigma_{ab}(g)}.
\end{align*}
Thus
\begin{align*}
A_{jb}\sigma(g)^{-1}w_a=\overline{\sigma_{ab}(g)}v_j.
\end{align*}
Therefore
\begin{align*}
(\rho(g)A_{jb}\sigma(g)^{-1}w_a,v_i)_V=\rho_{ij}(g)\overline{\sigma_{ab}(g)}.
\end{align*}
Hence
\begin{align*}
(T_{A_{jb}}w_a,v_i)_V=\int_G \rho_{ij}(g)\overline{\sigma_{ab}(g)}\,d\mu(g).
\end{align*}
If $(\rho,V)$ and $(\sigma,W)$ are not isomorphic, the previous Schur-lemma step gives $T_{A_{jb}}=0$, so the displayed integral is $0$.
Now assume $(\sigma,W)=(\rho,V)$ and the same [orthonormal basis](/page/Orthonormal%20Basis) is used. Then $m=n$, $w_a=v_a$, and $A_{jb}:V\to V$ satisfies $A_{jb}v_b=v_j$ and $A_{jb}v_c=0$ for $c\neq b$. Its trace is
\begin{align*}
\operatorname{tr}(A_{jb})=\delta_{jb}.
\end{align*}
The trace computation gives
\begin{align*}
T_{A_{jb}}=\frac{\delta_{jb}}{\dim V}I_V.
\end{align*}
Taking the $(i,a)$ matrix coefficient gives
\begin{align*}
(T_{A_{jb}}v_a,v_i)_V=\frac{\delta_{jb}}{\dim V}(v_a,v_i)_V=\frac{1}{\dim V}\delta_{ia}\delta_{jb}.
\end{align*}
Combining this with the already computed identity for $(T_{A_{jb}}w_a,v_i)_V$ proves
\begin{align*}
\int_G \rho_{ij}(g)\overline{\rho_{ab}(g)}\,d\mu(g)=\frac{1}{\dim V}\delta_{ia}\delta_{jb}.
\end{align*}
The two asserted orthogonality formulas follow.
[/step]