[guided]Reducedness means that a root line contains no roots except the two opposite roots. The main obstruction to exclude is the possible pair $\alpha,2\alpha$, because the integrality condition will reduce all other scalar-multiple possibilities to that one.
Assume first that $\alpha\in\Phi$ and $2\alpha\in\Phi$. We apply the [Root String Theorem][citetheorem:9728] to the string in the $\alpha$-direction through the root $\beta:=2\alpha$. The theorem applies here for the same reason as in the integrality step: $\alpha$ and $\beta$ are real roots obtained from the compact torus weight decomposition of the complexified adjoint representation, and the inner product is the invariant one used in the theorem statement. It gives integers $p,q\ge 0$ such that the roots on this line through $\beta$ are exactly
\begin{align*}
\beta-p\alpha,\beta-(p-1)\alpha,\dots,\beta+q\alpha
\end{align*}
and such that
\begin{align*}
p-q=\frac{2(\beta,\alpha)}{(\alpha,\alpha)}.
\end{align*}
Substituting $\beta=2\alpha$ gives
\begin{align*}
p-q=\frac{2(2\alpha,\alpha)}{(\alpha,\alpha)}=4.
\end{align*}
Because $q\ge 0$, we get $p=q+4\ge 4$. The meaning of $p\ge 4$ is that the string contains all roots from $\beta-p\alpha$ up to $\beta+q\alpha$, in particular it contains $\beta-2\alpha$. But
\begin{align*}
\beta-2\alpha=2\alpha-2\alpha=0.
\end{align*}
This is impossible, since $\Phi$ was defined using only non-zero weights. Hence no root has its double as a root.
Now suppose two roots lie on the same real line. Choose $\alpha,\beta\in\Phi$ and write $\beta=c\alpha$ with $c>0$. The Cartan-integer condition applied to $(\beta,\alpha)$ gives
\begin{align*}
\frac{2(\beta,\alpha)}{(\alpha,\alpha)}=2c\in\mathbb Z.
\end{align*}
The same condition applied to $(\alpha,\beta)$ gives
\begin{align*}
\frac{2(\alpha,\beta)}{(\beta,\beta)}=\frac{2c(\alpha,\alpha)}{c^2(\alpha,\alpha)}=\frac{2}{c}\in\mathbb Z.
\end{align*}
So both $2c$ and $2/c$ are positive integers. This forces $c\in\{1/2,1,2\}$. If $c=2$, then $\beta=2\alpha$, which has been excluded. If $c=1/2$, then $\alpha=2\beta$, also excluded. Therefore $c=1$. Including the negative direction, the only roots proportional to $\alpha$ are $\alpha$ and $-\alpha$. This is exactly the reducedness axiom.[/guided]